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The aim of this paper is to investigate different aspects of the seasonal-to-interannual temperature variability in Eastern Patagonia, the southernmost area of South America, east of the Andes Cordillera. Homogenous regions of seasonal variability and the atmospheric circulation patterns associated with warm and cold conditions in each of them are described in this study. Relationships between temperature in Eastern Patagonia and that registered in other areas of southern South America are also addressed. Results show that the northern and southern areas of Eastern Patagonia have different temperature variability in summer and autumn whereas the temperature variability tends to be more homogeneous within the region during winter and spring. Warm (cold) conditions in the northern areas are associated with reinforced (weakened) westerlies in summer, winter and spring whereas northerly (southerly) advections of warm (cold) air toward the region produce such conditions in autumn. Temperature in the southern portion of Eastern Patagonia is affected by anticyclonic (cyclonic) anomalies that enhance (reduce) the incoming solar radiation and induce reinforced (weakened) westerlies promoting warm (cold) conditions in the region. Furthermore, cyclonic (anticyclonic) anomalies at subpolar latitudes hinder (favor) outbreaks of cold air increasing (decreasing) the temperature over areas of Eastern Patagonia. The circulation anomalies associated with warm (cold) conditions in Eastern Patagonia also promote cold (warm) conditions over areas of northern Argentina, Paraguay and southern Brazil. Consequently, a dipole of temperature is detected in southern South America with centers of opposite sign over these regions.  相似文献   
74.
The existing United Nations Framework Convention on Climate Change (UNFCCC) has failed to deliver the rate of low-carbon technology transfer (TT) required to curb GHG emissions in developing countries. This failure has exposed the limitations of universalism and renewed interest in bilateral approaches to TT. Gaps are identified in the UNFCCC approach to climate change TT: missing links between international institutions and the national enabling environments that encourage private investment; a non-differentiated approach for (developing) country and technology characteristics; and a lack of clear measurements of the volume and effectiveness of TTs. Evidence from econometric literature and business experience on climate change TT is reviewed, so as to address the identified pitfalls of the UNFCCC process. Strengths and weaknesses of different methodological approaches are highlighted. International policy recommendations are offered aimed at improving the level of emission reductions achieved through TT.  相似文献   
75.
Sediment disturbance patterns in the coastal area off the Tagus Estuary (Portugal) have been assessed using a set of combined techniques. The potential sources of disturbance in the area include chronic contamination of the fine sediments originating from the estuary, a local input from a long-sea sewage outfall and occasional high runoff episodes following torrential rain. The Sediment Quality Triad approach, combining environmental chemistry (namely organic contaminants), macrofaunal benthic communities and laboratory sediment toxicity assays, was performed on sediment samples from 20 sites. The samples were collected before the outfall commenced operation and four years after commissioning, in order to evaluate the relative magnitudes of the three potential sources of disturbance. The sediment contamination created by the estuary was identified as the most important cause of reduced sediment quality, as disturbance in all three components of the Sediment Quality Triad were only found in a site located near the estuary.  相似文献   
76.
This study reports the longitudinal distribution of sediment properties, including inorganic and organic contaminants, and the structure of the benthic community in Obidos lagoon, a coastal system permanently connected to the sea and with negligible freshwater sources. Sediments from the upper to central lagoon consist of fine particles (91%) and from the lower lagoon of sands (94%). Chemical composition is strongly correlated to the percentage of fine particles. Contamination is relatively low in those sediments suggesting the effect of diffuse sources. The increase in organic matter content from down- to upstream areas was associated with the dominance of opportunistic species, while sensitive and indifferent species to organic enrichment were mainly associated to the clean sandy downstream area. The marine biotic index (AMBI) was suitable for the discrimination of the biological and environmental gradients in the Obidos lagoon and was highly related with the gradient of organic matter content in this system.  相似文献   
77.
The potential impact of deforestation in the Brazilian Amazon on greenhouse gas emissions to the atmosphere calls for policies that take account of changes in forest cover. Although much research has focused on the location and effects of deforestation, little is known about the distribution and reasons for the agricultural uses that replace forest cover. We used Landsat TM-based deforestation and agricultural census data to generate maps of the distribution and proportion of four major agricultural land uses throughout the Brazilian Amazon in 1997 and 2007. We built linear and spatial regression models to assess the determinant factors of deforestation and those major agricultural land uses - pasture, temporary agriculture and permanent agriculture - for the states of Pará, Rondônia, and Mato Grosso. The data include 30 determinant factors that were grouped into two years (1996 and 2006) and in four categories: accessibility to markets, public policies, agrarian structure, and environment. We found an overall expansion of the total agricultural area between 1997 and 2007, and notable differences between the states of Pará, Rondônia, and Mato Grosso in land use changes during this period. Regression models for deforestation and pasture indicated that determinant factors such as distance to roads were more influential in 1997 than in 2007. The number of settled families played an important role in the deforestation and pasture, the effect was stronger in 2007 than 1997. Indigenous lands were significant in preventing deforestation in high-pressure areas in 2007. For temporary and permanent agricultures, our results show that in 1997 the effect of small farms was stronger than in 2007. The mapped land use time series and the models explain empirically the effects of land use changes across the region over one decade.  相似文献   
78.
Numerical simulations and tests with the recently redesigned land–air parameterization scheme (LAPS) are presented. In all experiments, supported either by one-point micrometeorological, 1D or 3D simulations, the attention has been directed to: (1) comparison of simulation outputs, expressing the energy transfer over and through heterogeneous and non-heterogeneous surfaces, versus observations and (2) analysis of uncertainties occurring in the solution of the energy balance equation at the land–air interface. To check the proposed method for aggregation of albedo, “propagating hole” sensitivity tests with LAPS over a sandstone rock grid cell have been performed with the forcing meteorological data for July 17, 1999 in Baxter site, Philadelphia (USA). Micrometeorological and biophysical measurements from the surface experiments conducted over crops and apple orchard in Serbia, Poland, Austria and France were used to test the operation of LAPS in calculating surface fluxes and canopy environment temperatures within and above plant covers of different densities. In addition, sensitivity tests with single canopy covers over the Central Europe region and comparison against the observations taken from SYNOP data using 3D simulations were made. Validation of LAPS performances over a solid surface has been done by comparison of 2 m air temperature observations against 5-day simulations over the Sahara Desert rocky ground using 3D model. To examine how realistically the LAPS simulates surface processes over a heterogeneous surface, we compared the air temperature measured at 2 m and that predicted by the 1D model with the LAPS as the surface scheme. Finally, the scheme behaviour over urban surface was tested by runs over different parts of a hypothetical urban area. The corresponding 1D simulations were carried out with an imposed meteorological dataset collected during HAPEX-MOBILHY experiment at Caumont (France). The quantities predicted by the LAPS compare well with the observations and the various subcomponents of the scheme appear to operate realistically.  相似文献   
79.
The reactions of three structurally similar unsaturated alcohols, 2-buten-1-ol (crotyl alcohol), 2-methyl-2-propen-1-ol (MPO221) and 3-methyl-2-buten-1-ol (MBO321) with Cl atoms, have been investigated for the first time, using a 400 l Teflon reaction chamber coupled with gas chromatograph-coupled with flame-ionization detection (GC-FID). The experiments were performed at atmospheric pressure and at temperatures between 255 and 298 K, in air or nitrogen as the bath gas. The obtained kinetic data were used to derive the Arrhenius expressions , , (in units of cm3 molecule−1 s−1). Finally, atmospheric lifetimes of those unsaturated alcohols with respect to OH, NO3, O3 and Cl have been calculated.  相似文献   
80.
The effects of growth of autoirrigated, shaded transplants of Pseudoscleropodium purum on the quantification of tissue concentrations of Cd, Cu, Hg, V and Zn, were investigated in 4 exposure periods, each of 56 days, at 7 sampling sites (contaminated and uncontaminated). Concentrations of the elements in the basal portions of the moss shoots were compared with the concentrations in the portions of the shoots that grew during the exposure period. Mercury and V were present at lower concentrations in the new portions of the shoots than in the basal portions, whereas the opposite was true for Cd, Cu and Zn. The magnitude of error introduced by growth was not negligible, and in some cases was higher than 40%, relative to the results obtained by analysis of the whole shoot. Devitalization of moss prior to its use as transplant material is recommended to avoid growth of the plant during the exposure period.  相似文献   
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